Einstein's quantum theory of radiation revisited
In 1916 Einstein published a remarkable paper entitled "On the
Quantum Theory of Radiation" [1]-[3] where he derived Planck's formula
for black-body radiation by a new statistical hypothesis for the
emmision and absorption of electromagneic radiation based on discrete
bundles of energy and momentum which we now call photons. Einstein
radiation theory replaced Maxwell's classical theory by a stochastic
process, and in this talk I will show that it also gives the well
known quantum statistics of massless particles with even spin [2].
These statistics however, were not discovered by Einstein but communicated
to him by Bose in 1924. Like Boltzmann's classical counterpart,
Einstein's statistical theory leads to an irreversible approach
to thermal equilibrium, but because this violates time reversal,
Einstein theory can not be regarded as a fundamental theory of physical
processs [2]. Apparently Einstein and his contemporaries were unaware
of this problem, and even today this problem is ignored in contemporary
discussions of Einstein's treatment of the black-body spectrum.
References:
[1] A. Einstein "On the Quantum theory of Radiation" Phys.
Zeitschrift 18 (1917) 121. First printed in
Mitteilungender Physikalischen Gesellschaft Zurich. No
18, 1916. Translated into English in Van der Waerden
Sources of Quantum Mechanics (North Holland 1967) pp. 63-77.
[2] M. Nauenberg, " The evolution of radiation towards thermal
equilibrium: A soluble model which illustrates the foundations of
statistical mechanics" American Journal of Physics 72
(2004) 313
[3] D. Kleppner, "Rereading Einstein on Radiation" Physics
Today, February 2005 , p. 30 |